Formation of two (6,3) networks showing structural diversity, Borromean topology and conformational chirality in the same crystal.

نویسندگان

  • Xue-Li Zhang
  • Cui-Ping Guo
  • Qing-Yuan Yang
  • Wei Wang
  • Wei-Sheng Liu
  • Bei-Sheng Kang
  • Cheng-Yong Su
چکیده

Reaction of two tripodal ligands, 2,4,6-tris(4-((2-methyl-benzimidazol-1-yl)methyl)phenyl)-1,3,5-triazine (L1) and 1,3,5-tris(4-((2-methyl-benzimidazol-1-yl)methyl)phenyl)benzene (L2), with AgSbF6 led to formation of two types (6,3) networks in one single crystal, of which one is three-fold Borromean topologically entangled while the other is independent, showing the same chirality and sandwiched Borromean stacking.

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عنوان ژورنال:
  • Chemical communications

دوره 41  شماره 

صفحات  -

تاریخ انتشار 2007